For me it's goetia and exorcisms(there would probably be more on my list). Goetia mostly works with daemons, and not all of these 72 entities are nice. Exorcism is the riskiest thing(in my opinion) you can attempt if you don't know 100% what you're doing. IF it is an entity possessing someone, it won't let go easily, And often try to psychologically torment you. That's why exorcisms are often done by highly experienced priest. And someone could mistake mental illness for demonic possession most of the times as well. It happen in those early days very often.
But anyways, for me I know goetic invocation and exorcisms are 2 nasty businesses. How about you?